scienceneutral

Single‑Atom Strategy Keeps Nickel Active in Sulfur‑Rich Methane Production

Friday, July 3, 2026

Nickel is a stellar catalyst for converting carbon monoxide and dioxide into methane, but it has a fatal flaw: it grabs sulfur so tightly that the catalyst gets poisoned.
Scientists have solved this by introducing single ruthenium atoms into the nickel lattice, effectively creating a decoy that protects the active sites.

  • How it works
  • Ruthenium atoms attract sulfur because they pull a bit more electron density.
  • Once sulfur binds to ruthenium, the strong interaction prevents it from dissociating into reactive fragments that would poison nickel.
  • This keeps nearby nickel sites clean and fully active for methane production.
  • Performance
  • The new alloy tolerates up to 10 parts per million (ppm) of hydrogen sulfide without losing activity.
  • Plain nickel, in contrast, shuts down quickly under the same conditions.

  • Broader impact
    The strategy of spatially separating sulfur‑binding sites from catalytic ones could safeguard a wide range of metal catalysts against sulfur poisoning.

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